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2025 (Current Year) Faculty Courses School of Materials and Chemical Technology Department of Chemical Science and Engineering Graduate major in Chemical Science and Engineering

Advanced Molecular Catalyst Chemistry II

Academic unit or major
Graduate major in Chemical Science and Engineering
Instructor(s)
Yumiko Nakajima
Class Format
Lecture (Face-to-face)
Media-enhanced courses
-
Day of week/Period
(Classrooms)
3-4 Thu (S3-206(S323))
Class
-
Course Code
CAP.A428
Number of credits
100
Course offered
2025
Offered quarter
4Q
Syllabus updated
Sep 19, 2025
Language
English

Syllabus

Course overview and goals

This lecture explains the diverse reaction mechanisms of organometallic catalytic reactions, including the latest research reports.
Based on the understanding the mechanisms of a series of organometallic catalytic reactions, students can learn techniques to control these reactions. The goal is to cultivate the ability to design organometallic catalytic reactions.

Course description and aims

1) Explain the mechanisms of various organometallic catalytic reactions.
2) Propose useful organometallic catalysts for developing new catalytic reactions.

Keywords

Reaction Mechanism, Kinetics, Organometallic Compounds, Metal Complex, Molecular Catalysts

Competencies

  • Specialist skills
  • Intercultural skills
  • Communication skills
  • Critical thinking skills
  • Practical and/or problem-solving skills

Class flow

To enhance effective learning, students are encouraged to spend approximately 100 minutes preparing for class and another 100 minutes reviewing class content afterwards (including assignments) for each class.

Course schedule/Objectives

Course schedule Objectives
Class 1

C-H bond cleavage as the key step for catalytic reactions

Be able to explain direct C-H bonds transformation catalyzed by organometal catalysts

Class 2

Metal-ligand cooperation

Be able to explain the catalytic reactions utilizing metal-ligand cooperation functions of organometal catalysts

Class 3

Photoredox catalyst

Be able to explain the catalytic conversion reactions of organic molecules using photoredox catalysts.

Class 4

Activation of small molecules

Be able to explain small molecule activation such as nitrogen and CO2

Class 5

Material design

Be able to explain insertion polymerization and stereocontrol in polymer synthesis; Be able to explain the molecular design of high performance silicone materials.

Class 6

Polymer Recycling

Be able tp explain polymer degradation and reuse utilizing organometallic catalysts, as well as polymer upcycling.

Class 7

exam

Study advice (preparation and review)

To enhance effective learning, students are encouraged to spend approximately 100 minutes preparing for class and another 100 minutes reviewing class content afterwards (including assignments) for each class.
They should do so by referring to textbooks and other course material.

Textbook(s)

DAIGAKUIN KOUGI YUUKI KAGAKU I (TOKYO KAGAKU DOJIN)

Reference books, course materials, etc.

Organotransition Metal Chemistry From Bonding to Catalysis, University Science Book

Evaluation methods and criteria

Final exam (70%), class participation (30%) (Class participation will be calculated based on quizzes during class, etc.)

Related courses

  • CAP.A561 : Advanced Chemistry of Transition Metal Complexes I
  • CAP.I403 : Advanced Coordination Chemistry
  • CAP.A464 : Advanced Molecular Design of Metal Complexes II
  • CAP.A562 : Advanced Chemistry of Transition Metal Complexes II
  • CAP.A463 : Advanced Molecular Design of Metal Complexes I

Prerequisites

None

Office hours

contact by e-mail in advance