2024 Faculty Courses School of Materials and Chemical Technology Undergraduate major in Materials Science and Engineering
Organic Materials Structures A
- Academic unit or major
- Undergraduate major in Materials Science and Engineering
- Instructor(s)
- Toshiaki Ougizawa
- Class Format
- Lecture (Face-to-face)
- Media-enhanced courses
- -
- Day of week/Period
(Classrooms) - 3-4 Fri
- Class
- -
- Course Code
- MAT.P221
- Number of credits
- 100
- Course offered
- 2024
- Offered quarter
- 4Q
- Syllabus updated
- Mar 17, 2025
- Language
- Japanese
Syllabus
Course overview and goals
This course focused on the basics of polymer structure, especially 1.Shape and size of polymer chain, 2.Elasticity of polymer, 3.Polymer solutions. At first, relation between the structure and applications in the organic materials is explained.
When we use polymers as materials, the control of the physical properties is important. Therefore, it is necessary to know the basic structure of polymers and control the structure for physical properties. It is desirable to understand the basic of the essence of polymers.
Course description and aims
By the end of this course, students will be able to understand:
1)Structure from single chain to aggregate (bulk state) in polymer
2)Physicochemical mechanism of structure formation in polymer
3)Basics of mechanism that physical properties appear in polymeric materials
Student learning outcomes
実務経験と講義内容との関連 (又は実践的教育内容)
When a polymer is used as an actual material, it is important to control its physical properties. For that purpose, it is necessary to know the basic structure and control the structure based on that knowledge. It is very important to understand the content of this lecture as the first entry point (basic) for doing so.
Keywords
Random coil, Configuration, Conformation, Mean square of end-to-end distance, Mean square of radius of gyration, Freely joint chain, Freely rotating chain, Ideal chain, Gaussian chain, Entropy elasticity, Dilute solution, Semi-dilute solution, Concentrated solution, Excluded volume effect, Interaction parameter, Solubility parameter, Floy-Huggins equation, Phase diagram, Binodal, Spinodal, Critical point, Phase separation
Competencies
- Specialist skills
- Intercultural skills
- Communication skills
- Critical thinking skills
- Practical and/or problem-solving skills
Class flow
Based on power point files, I push forward a lecture with a question. In addition, at the beginning of each class, solutions of quiz (small test) in previous class are reviewed. Towards the end of class, students are given quiz related to the lecture given that day to solve.
Course schedule/Objectives
| Course schedule | Objectives | |
|---|---|---|
| Class 1 | Introduction: Characteristics of the structure and applications in the organic materials | Relation between structure (and size) of polymer chain and applications |
| Class 2 | Structure of polymer chain: Configuration and conformation | Kinds of first order structure in polymer chain |
| Class 3 | Structure of polymer chain: Shape and size of single polymer chain | Derivation of size of random coil |
| Class 4 | Elasticity of polymer (Entropy elasticity) | Relation between structure of polymer chain and entropy elasticity |
| Class 5 | Polymer solutions: Dilute, semi-dilute and concentrated solutions | Classification of polymer solution by concentration and its physical properties |
| Class 6 | Polymer solutions: Thermodynamics of phase diagram | Derivation of free energy in polymer solution |
| Class 7 | Polymer solutions:Phase separation | Mechanism of phase separation |
Study advice (preparation and review)
To enhance effective learning, students are encouraged to spend approximately 100 minutes preparing for class and another 100 minutes reviewing class content afterwards (including assignments) for each class.
They should do so by referring to textbooks and other course material.
Textbook(s)
Copy of Power Point files (Materials used in class can be found on T2SCHOLA)
Reference books, course materials, etc.
Reference books: P.J.Floy, "Principles of Polymer Chemistry" (Cornell University Press)
Evaluation methods and criteria
Evaluation is carried out by quizzes of every time, some reports and a term-end examination.
Related courses
- MAT.P321 ： Organic Materials Structures B
Prerequisites
No prerequisites are necessary. If possible, it is preferable to take a lecture on the basics of thermodynamics.