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2021 Faculty Courses School of Science Department of Chemistry Graduate major in Chemistry

Basic Concepts of Inorganic Chemistry

Academic unit or major
Graduate major in Chemistry
Instructor(s)
Masaki Kawano / Hiroyuki Kawaguchi / Osamu Ishitani / Takayuki Komatsu / Masatomo Yashima / Hidehiro Uekusa / Kazuhiko Maeda
Class Format
Lecture
Media-enhanced courses
-
Day of week/Period
(Classrooms)
5-6 Mon / 5-6 Thu
Class
-
Course Code
CHM.B401
Number of credits
200
Course offered
2021
Offered quarter
2Q
Syllabus updated
Jul 10, 2025
Language
English

Syllabus

Course overview and goals

This course focuses on core knowledge about inorganic chemistry and analytically chemistry. This represents a detailed discussion of molecular absorption on solid surface, analytical methods for solid surface and bulk solids, crystal structures and solid state photoreaction of organometallic complexes, coordination compounds, and metal clusters. The aim of this course is to get students to gain core knowledge and basic skills in a comprehensive and systematic way on the basis of their undergraduate inorganic/analytical chemistry courses. The knowledge and skills acquired through this course will help students to study in their specialized fields.

Course description and aims

By the end of this course, students will be able to:
1) Explain properties of inorganic compounds
2) Explain molecular structures and properties of organometallic complexes
3) Understand the structural characterization of solids by X-ray, electron and neutron diffraction
4) Understand photochemistry of coordination coupounds

Keywords

photochemical reaction, chemistry of catalysis, coordination chemistry, organometallic chemistry, crystal chemistry

Competencies

  • Specialist skills
  • Intercultural skills
  • Communication skills
  • Critical thinking skills
  • Practical and/or problem-solving skills

Class flow

This course will be given in a omnibus form.

Course schedule/Objectives

Course schedule Objectives
Class 1

Adsorption of molecules onto solid surface, physical and chemical adsorption, adsorption isotherm, adsorption equilibrium, coverage, Langmuir adsorption

Derive adsorption isotherms by understanding of adsorption on solid surface.

Class 2

IR spectra of adsorbed molecules, base molecules adsorbed on acid sites, CO adsorbed on metal surface

Estimate the concentration and strength of acid sites and dispersion of metals through IR spectra of adsorbed molecules.

Class 3

Analysis of adsorbed species on solid surfaces by means of temperature-programmed desorption

Explain the basic principle and specific feature of temperature programmed desorption by showing a concrete example

Class 4

Analysis of solid surface by X-ray photoelectron spectroscopy

Explain analysis of solid surface by X-ray photoelectron spectroscopy

Class 5

Structural characterization of solids by X-ray, electron and neutron diffraction

Understand the structural characterization of solids by X-ray, electron and neutron diffraction

Class 6

Introduction to organometallic complexes

Explain properties of organometallic complexes.

Class 7

Molecular structures of organometallic complexes

Explain molecular structures of organometallic complexes.

Class 8

Crystal structures of organometallic complexes

Explain crystal structures of organometallic complexes.

Class 9

Solid-sate reaction mechanism of metal-organic compound

Understanding of solid-sate reaction mechanism and analysis method

Class 10

Solid-state photo-reaction of metal-organic compound

Understanding of solid-state and crystalline state photo-reaction
mechanism and controlling using three dimensional structure
information

Class 11

Coordination compounds-metals and ligands

Explain bonding in coordination compounds

Class 12

Coordination compounds-3d metals

Explain properties of 3d metal complexes

Class 13

Inorganic compounds consisting of d and f block elements and their functionality – The basic principle of the functionality

Understanding : photophysical and photochemical properties of coordination compounds

Class 14

Inorganic compounds consisting of d and f block elements and their functionality – Specific feature of each class of coupounds

Understanding photocatalytic abilities of coordination compounds

Study advice (preparation and review)

To enhance effective learning, students are encouraged to spend approximately 100 minutes preparing for class and another 100 minutes reviewing class content afterwards (including assignments) for each class.
They should do so by referring to textbooks and other course material.

Textbook(s)

Course materials are provided during class.

Reference books, course materials, etc.

Shriver and Atkins, Inorganic Chemistry

Evaluation methods and criteria

Students' knowledge of basic topics of inorganic and analytical chemistry covered in the course will be assessed by reports (40%) and final exam (60%).

Related courses

  • CHM.B201 : Inorganic Chemistry I
  • CHM.B301 : Inorganic Chemistry II
  • CHM.B202 : Basic Analytical Chemistry
  • CHM.B332 : Photochemistry
  • CHM.B333 : Crystal Chemistry
  • CHM.B335 : Chemistry of Solids

Prerequisites

No prerequisites